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12
6
Evolutionary line
Nearsurf a ce
riparian
y = 2.846 2e 0. 5552x
R 2 =0.85
10
5
8
4
6
Deepriparian
groundwater
3
Baseflow
Storm started
1.5 hrs afterpeak storm
Storm end
Poststorm
4
2
Baseflow
Stormstarted
15 hrs afterpeak storm.
Stormend
Poststorm
2
1
Hillslope
soilwater
0
0
0
0.2
0.4
0.6
0.8
1
0
2
4
6
8
10
12
Proportion of runoff (unitless)
Ca 2+ (mg/L)
(a)
(b)
Fig. 4. Relationship between contribution of NSR to runoff and change of stream Ca 2+
concentration (a) and mixing diagram of Ca 2+ and SiO 2 during August 21-22, 2001
storm.
6
DRG
HSW
NSR
5
4
NSR
3
DRG
2
1
HSW
0
0
2
4
6
8
Total discharge (L/s)
Fig. 5. Relationship between discharge and Ca 2+ flux during storm event on August 21-
22, 2001. NSR: near surface riparian; DRG: deep riparian groundwater; HSW: hillslope
soil water.
in the NSR suggesting that the rate of transport was superior to that of
dilution of the weathered Ca 2+ .
Those phenomena explain well that Ca 2+ has progressively deteriorated
during the hydrologic event. As discharge increased Ca 2+ flux increased
linearly (Fig. 5). The Ca 2+ flux in the NSR was higher than that in the
DRGaswellasintheHSW.Intheriparianzone,Ca 2+ concentration
increased away from the stream and decreased at the border between the
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