Biomedical Engineering Reference
In-Depth Information
Reaction 3.2 The
hydrochloric acid-dependent
conversion of Hcy to Hcy-
thiolactone (Reprinted from
[68])
N
H
2
.
N
H
2
HCl
O
HCl, 100
o
C
-H
2
O
OH
O
SH
S
Fig. 3.2 Synthesis of
D
,
L
-Hcy-thiolactone and its enantiomeric resolution (with HTL representing
Hcy-thiolactone in the figure). (a) Time course of the synthesis of
D
,
L
-Hcy-thiolactone from
L
-Met. Here 30-
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