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Compound
Representative
Cell Parameter ( ˚ )
Rare Earth, Co.
No., Average Bond
Distance ( ˚ )
Tetrahedral
Radical Form
Rare Earth Polyhedra
b 5 7.387
c 5 7.120
K 3 RSi 6 O 15
K 3 NdSi 6 O 15
Pbam z 5 4
Nd
6
2.38
Layers with 8-, 6-, 5-,
and 4-membered
rings
Discrete polyhedra
R 5 La Lu
a 5 16.011
b 5 14.984
c 5 7.276
K 8 R 3 [Si 6 O 16 ] 2
P1 z 5 l
Yb
6
2.26
Layers with 12-, 8-,
and 6-membered
rings
Discrete and bicapped
polyhedra
(OH)
K 8 Yb 3 [Si 6 O 16 ] 2
a 5 6.808
R 5 La Lu
(OH)
b 5 11.434
c 5 11.449
α 5 88.52
β 5 90.91
γ 5 100.10
K 2 Ce[Si 6 O 15 ]
12/b z 5 4
Ce
8
2.23
Framework
Discrete
a 5 13.058
b 5 11.854
c 5 8.698
γ 5
90.15
Co. No. 5 coordination number
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