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Cell Parameter ( ˚ )
Compound
Representative
Rare Earth, Co.
No., Average Bond
Distance ( ˚ )
Tetrahedral
Radical Form
Rare Earth Polyhedra
b 5 12.741
c 5 8.441
Na 5 RSi 4 O 12
Na 5 LuSi 4 O 12
R32 z 5 16
Lu
6
2.20
12-Membered
Discrete polyhedra
R 5 Sm Lu, Y, Sc
a 5 21.926 [4]
ring
c 5
12.556 [2]
LiScSi 2 O 6
C2/cz 5 4
Sc
6
2.107
Chains with period
of 2 tetrahedral
Layer
a 5 9.8033
b 5 8.9581
c 5 5.3512
β 5 110.281
Na 12 Y 4 Si 12 O 36
P2 I 2 I 2 I z 5 16
Y
6
2.20
Chains with period
of 24 tetrahedral
Discrete polyhedra
a 5 15.033
2 2.36
b 5 15.142
c 5 15.213
NaRSi 6 O 14
NaPrSi 6 O 14
Ibam z 5 8
Pr
6
2.41
Triple layered column
Column
R 5 La Lu
a 5 7.682
b 5 15.445
c 5 19.724
NaNdSi 6 O 13
Cmm2 z 5 4
Nd
7
2.44
Layers with 8-, 6-, 5-,
and 4-membered
rings
Discrete polyhedra
(OH) 2 nH 2 O
a 5 30.87
(Continued)
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