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˛ fm .a;R/e ˇU.R/
˛.a/ D
;
(3.185)
R
˛ fm .a;R/e ˇU.R/
4D
e ˇU.r 0 / dr 0
r 0 2
1 C
The numerical calculations were performed for the potential from Lushnikov
and Kulmala ( 2004a ) that includes Coulomb C image forces with q D Q D 1 and
l c D l or l c D 3l.
The results are presented in Figs. 3.19 and 3.20 in terms of the correction factors
.a/, the ratios of the charging efficiencies found from Eq. 3.176 to their values in
the free molecule regime.
˛.a/
˛ fm .a/ ;
.a/ D
(3.186)
4.0
3.5
l c =1
l c =3
3.0
2.5
2.0
1.5
1.0
0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
PARTICLE RADIUS a (in units of l )
Fig. 3.19
Correction factor .a/
D
˛.a/=˛ fm.a/ for ion-particle recombination as a function of
particle radius (in units of l
D
2D= v T ). Solid and dotted curves display R.a/ for l c
D
1 and
l c
3, respectively. It is seen that even at small particle sizes these curves deviate from unity; i.e.,
the free molecule approximation is noticeably corrected by ion-carrier gas interaction l c
D
/
l
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