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confinement of chiral ligands in metallacyclic supramolecules seems
to be a promising approach to enantioselective recognition of chiral
substrates.
Cl
Cl
CO
CO
OC
OC
Re
N
N
Re
CO
Cl
Cl
ORRO
N
N
Cl
Cl
3h
OR
OR
RO
RO
R = H, Et, CH
2
Ph, and
Me
Me
Si
Cl
Cl
tert-butyldimethylsilyl
N
N
ORRO
OC
CO
N
N
Re
CO
OC
Cl
Re
Cl
CO
CO
Cl
Cl
−
6
Figure 10.7
Stern
−
Volmer plots of (R)-
3h
(2.2
×
10
M) in the presence
of
(S)-
and
(R)-2-amino-1-propanol.
Reproduced
with
permission from Ref. [44].
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