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Z i
=
a
e
-
i
b
(vii)
The two undetermined multipliers a and b can be evaluated from eqs. (i)
and (ii):
Â
e -
i
b
a
=
Z
(viii)
Â
a
i
e -
i
b
=
N
(ix)
Remembering that
d
db
Â
Â
-
i
b
-
i
b
-
e
=
i
e
we obtain from (viii) and (ix) after some manipulation:
Z
n
(
) ª
a=
Z
1
-
e
-
1
n
(x)
11
nn
Ê
Ë
ˆ
¯ ª
b=
ln 1
+
(xi)
where n , the mean cell population or density N / Z is assumed to be large in
order to obtain the simple approximations. In other words, cells are
assumed to be large enough to lodge plenty of elements.
Having determined the multipliers a and b, we have arrived at the most
probable distribution which, after eq. (vii) now reads:
Z
n
Z
=
e
-
in
(xii)
i
From eq. (iv) we obtain at once the maximum entropy:
H = ()
ln
en
.
(xiii)
Clearly, if the elements are supposed to be able to fuse into pairs (Fig. 7 b ),
we have
(
)
HZ ln
¢=
en 2
.
(xiv)
Equating
H
with H m and
H
¢ with H , we have for the amount of order after
fusion:
()
Z
Z
ln
ln
en
en
1
R
=-
1
) =
(xv)
(
()
2
log
en
2
References
1. L. Wittgenstein, Tractatus Logico-Philosophicus , paragraph 6.31, Humanities
Publishing House, New York (1956).
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