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FIGURE 7.
whence we obtain the entropy of the system for a large number of cells and
elements:
== Â
HPZZ ZZ
i
ln
ln
ln
(iv)
i
In the case of maximum entropy
H
we must have
d H = 0
(v)
observing also the conditions expressed in eqs. (i) and (ii). Applying the
method of the Lagrange multipliers we have from (iv) and (v) with (i) and
(ii):
Â
Â
Â
(
)
ZZ
iZ
Z
ln
+
1
d
=
0
i
i
d
=
=
0
0
b
i
|
(
)
d
- +
1
ln
a
i
multiplying with the factors indicated and summing up the three equations
we note that this sum vanishes if each term vanishes identically. Hence:
ln
Zi
i ++ -- =
1
b
1
ln
a
0
(vi)
whence we obtain that distribution which maximizes H :
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