Evaluation of Antifouling Booster Biocides in MarineWater and Sediments Based onMass Spectrometric Techniques - Antifouling Paint Biocides - page 128

Table 1 (continued)

LOD (LOD, ng L -1

Antifouling Matrix Extraction method Recovery GC Ionization Detection Mode Refs.

booster (sorbent) (%) Capillary mode system operation in seawater and

ng g -1 biocides column in sediment)

[28] ∗ seawater SPE (polymeric) 78 HP-5 NCI Q-MS SIM 0.5

[28] ∗ seawater SPE (polymeric) 78 HP-5 EI Q-MS SIM 2.5

[23] ∗

seawater SME 94 DB-5 ECD 2.0

[14] ∗ sediments LLE (dichloro- EI MS SIM 500

methane / acetone)

[35] ∗

sediments sonication / LLE 92 DB-1 EI Q-MS SIM 2.5

[26] ∗ sediments water extraction / 37 DB-5 EI Q-MS SIM 25

SPME (PDMS)

[26] ∗

sediments acetone extraction / 74 DB-5 EI Q-MS SIM 6

SPME (PDMS)

[14] ∗ Dichlofluanid seawater LLE (dichloro- EI MS SIM 200

methane)

[27] ∗

seawater SPE (polymeric) 53 HP-5 NCI IT-MS MS / MS 5.0

[28] ∗ seawater SPE (polymeric) 53 HP-5 NCI Q-MS SIM 1.5

[28] ∗ seawater SPE (polymeric) 53 HP-5 EI Q-MS SIM 2.5

[20] ∗

seawater, SPE (PLRP-S) 67 HP-5 EI Q-MS SIM 20

ports
seawater

SPE 72 HP-5 EI IT-MS SIM 3 [34]

∗ simultaneousdetermination:([22]:I,D;[21]:I,S;[24]:I,S;[20]:I,D;[14]:I,C,D;[35]:I,C,D;[23]:C,D,S;[27]:I,C,D,S,T;[28]:I,D,S,
T; [26]: I, C, D, S). I: Irgarol 1051, C: Chlorothalonil, D: Dichlofluanid, T: TCMTB, S: Sea-nine 211.
a

reported recovery of internal standard TPT (tripropyl tin chloride)