Evaluation of Antifouling Booster Biocides in MarineWater and Sediments Based onMass Spectrometric Techniques - Antifouling Paint Biocides - page 127

Table 1 (continued)

LOD (LOD, ng L -1

Antifouling Matrix Extraction method Recovery GC Ionization Detection Mode Refs.

booster (sorbent) (%) Capillary mode system operation in seawater and

ng g -1 biocides column in sediment)

[22] ∗ seawater, SPME (polyacrylate) HP-1 EI Q-MS SIM 50

harbour
seawater

[21] ∗

SPME (PDMS-DVB) 90 DB-5 ECD 2

[21] ∗ seawater SPME (PDMS-DVB) 90 DB-1 FTD 20

[24] ∗ seawater HS-SPME 118 DB-5 EI Q-MS SIM 30

sediments LLE (dichloro- EI MS SIM 500 [14]

methane / acetone)

[35] ∗ sediments sonication / LLE 82 DB-1 EI Q-MS SIM 0.7

sediments soxhlet / acetone 61 SE-54 AFID 0.05 [37]

[26] ∗ sediments water extraction / 66 DB-5 EI Q-MS SIM 8.0

SPME (PDMS)

[26] ∗ sediments acetone extraction / 91 DB-5 EI Q-MS SIM 0.5

SPME (PDMS)

sediments MAE 85.4 ZB-5 EI IT-MS SIM 1.7 [25]

sediments SFE 87 DB-225 MS SIM 3.0 [38]

[14] ∗

Chlorothalonil seawater LLE (dichloro- EI MS SIM 200

methane)

[27] ∗

/

seawater SPE (polymeric) 78 HP-5 NCI IT-MS MS MS 0.05

∗ simultaneousdetermination:([22]:I,D;[21]:I,S;[24]:I,S;[20]:I,D;[14]:I,C,D;[35]:I,C,D;[23]:C,D,S;[27]:I,C,D,S,T;[28]:I,D,S,
T; [26]: I, C, D, S). I: Irgarol 1051, C: Chlorothalonil, D: Dichlofluanid, T: TCMTB, S: Sea-nine 211.
a

reported recovery of internal standard TPT (tripropyl tin chloride)