Chemistry Reference
In-Depth Information
Fig. 10.16 Temperature dependence of the electrical conductivity at stage 1 (
black
), 2 (
red
),
and 3 (
blue
)ofK
2
(B)[Pt
2
(pop)
4
I]
(a)NC
3
N
2+
, b) Me-NC
3
N
2+
,
(c) Cl-NC
3
N
2+
,(d)
cis
-NC
4
N
2+
,(e)
trans
-NC
4
N
2+
,(f)NC
5
N
2+
, and (g)NC
2
OC
2
N
2+
4H
2
O, where B
2+
¼
Table 10.4
s
RT
(RT
¼
298 K) and
E
a
at high temperature of K
2
(B)[Pt
2
(pop)
4
I]
4H
2
O measured
in each stage
RT
/S cm
1
(RT
s
¼
298 K)
E
a
/meV
Stage 1
Stage 2
Stage 3
Stage 1 Stage 2 Stage 3
10
4
10
3
10
5
K
2
(NC
3
N)[Pt
2
(pop)
4
I]
1.5
1.4
8.0
226
122
196
4H
2
O
10
5
10
3
10
6
K
2
(Me-NC
3
N)
[Pt
2
(pop)
4
I]
3.3
3.3
6.9
319
119
240
4H
2
O
10
4
10
3
10
4
K
2
(Cl-NC
3
N)[Pt
2
(pop)
4
I]
2.8
3.3
1.5
161
120
167
4H
2
O
10
3
10
3
10
5
K
2
(
cis
-NC
4
N)[Pt
2
(pop)
4
I]
4.0
1.0
3.3
174
122
151
4H
2
O
10
4
10
3
10
4
K
2
(
trans
-NC
4
N)
[Pt
2
(pop)
4
I]
8.4
9.4
1.2
169
96
195
4H
2
O
10
3
10
4
10
5
K
2
(NC
5
N)[Pt
2
(pop)
4
I]
4.4
1.6
3.2
145
126
148
4H
2
O
10
3
K
2
(NC
2
OC
2
N)
[Pt
2
(pop)
4
I]
4H
2
O
1.6
200
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