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(a)
(b)
10
10
9
9
C A
8
C A
8
7
7
6
6
5
5
4
4
3
3
C B
2
2
1
1
C B
0
0
0123456789 0
0.0
0.2
0.4
0.6
0.8
1.0
k S t
k S t
(c)
(d)
1.0
1.0
0.9
0.9
0.8
0.8
A
0.7
0.7
0.6
0.6
A
j
j
0.5
0.5
0.4
0.4
B
0.3
0.3
0.2
0.2
0.1
0.1
B
0.0
0.0
0.0
0.2
0.4
0.6
0.8
1.0
0123456789 0
k S t
k S t
FIGURE E9-4.4 Variations of concentrations in the bulk phase (a, b) and surface coverages (c, d) as functions of
time for k A C s ¼
k S ; K A ¼
1/ C s ; K C ¼
4; K B ¼
1/ C s ; and k B C s ¼
10 k S .
(a)
(b)
10
1.0
9
0.9
C A
8
0.8
7
0.7
6
0.6
j
5
0.5
4
0.4
A
3
0.3
2
0.2
B
1
C B
0.1
0
0.0
0.01
0.1
1
10
100
0.01
0.1
1
10
100
k S t
k S t
FIGURE E9-4.5 Variations of concentrations in the bulk phase (a) and surface coverages (b) for k A C s ¼ 0.1 k S ;
K A ¼
1/ C s ; K C ¼
4; K B ¼
1/ C s ; and k B C s ¼
k S .
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