Chemistry Reference
In-Depth Information
R
Ar
R
1
R
2
PPh
2
PPh
2
Fe
Fe
X
Fe
PPh
2
PPh
2
PPh
2
Ph
2
P
Ar
R
MandyPhos (FERRIPHOS)
(
R
)-(
S
)-
84
:R=Me,Ar=Ph
(
R
)-(
S
)-
85
:R=Me,Ar=
o
-Tolyl
(
R
)-(
S
)-
86
:R=Me,Ar=2-Np
(
R
)-(
S
)-
87
:R=
i
Pr, Ar = Ph
(
R
)-(
S
)-
88
:R=N(Me)
2
,Ar=Ph
TaniaPhos
(
R
,
S
)-BPPFA: X = NMe
2
(
R,S
)-BPPOH: X = OH
N(H
3
C)(H
2
C)
2
NN
89
:R
1
=NMe
2
,R
2
=H
90
:R
1
=N-pyrrolidyl,R
2
=H
91
:R
1
=Me,R
2
=H
92
:R
1
=
i
Pr, R
2
=H
93
:R
1
=H, R
2
=OMe
(
R
)-(
S
)-
83
X=
PR
1
2
R
2
2
P
CH
3
PR
1
2
R
PR
2
2
N
PPh
2
Fe
Fe
PR'
2
Fe
JosiPhos: R
1
=Cy,R
2
BoPhoz
97
:R=H,R'=Ph
98
:R=Me,R'=Ph
99
:R=Et,R'=Ph
100
:R=Pr,R'=Ph
101
:R=Me,R'=Cy
=Ph
WalPhos
PPF-
t
Bu
2
:R
1
=
t
Bu, R
2
=Ph
95
:R
1
=Ph,3,5-Me
2-4
-MeOC
6
H
2
96
:R
2
=3,5-(CF
3
)
2
C
6
H
3
XyliPhos: R
1
=3,5-Me
2
Ph, R
2
=Ph
cy
2
PF-Pcy
2
:R
1
=Cy,R
2
=Cy
94
:R
1
=
t
Bu, R
2
=4-CF
3
Ph
PPh
2
PR
2
CHEt
2
PPh
2
PPh
2
Ph
PPh
2
PMe
2
N
Fe
Fe
Fe
Fe
N
N
Fe
PPh
2
CHEt
2
R
2
P
102
ClickFerroPhos
R=Et,Pr,Bu,Ph
(
S
,
S
)-FerroPhos
(
R,R)
-(
S,S)
-TRAP
O
PPh
2
N
O
P
P
R
O
O
Fe
O
P
Fe
O
(
R
,
R
)-
105
(
S
c
,R
p
,S
a
)
-103
:R=Me
(
S
c
,R
p
,S
a
)
-104
:R=H
Figure 7.12.
Ferrocene - based ligands.
