Chemistry Reference
In-Depth Information
Ph
O
N
N
O
N
o
-Tol
(
o
-tol)
2
P
PAr
2
N
N
t
Bu
t
Bu
R
PHOX
PyrPHOX
PHIM
S
O
O
(
o
-tol)
2
P
S
O
N
(R
2
)
2
P
N
R
1
i
Pr
N
(R
2
)
2
P
65
R
1
HetPhoX
66
:R
1
t
Bu, R
2
68
:R
1
t
Bu, R
2
=
=
o
-Tol
=
= Ph
67
:R
1
i
Pr, R
2
69
:R
1
t
Bu, R
2
=
= Cy
=
=
o
-Tol
R
1
PPh
2
O
Cy
O
R
1
*
N
N
N
(R
2
)
2
P
Ph
R
2
P
N
Cy
Cy
70
:R
1
= Ph, R
2
t
Bu
=
Ph
71:
R
1
t
Bu, R
2
=
=
o
-Tol
74
:R
1
= R
2
= H
75
:R
1
-R
2
=CH-CH=CH-CH
BIPI 153
72:
R
1
t
Bu, R
2
=
= Cy
73:
R
1
t
Bu, R
2
t
Bu
=
=
H
O
O
(
o
-Tol)
2
P
N
P
N
O
R
t
Bu
Ph
2
P
N
CHPh
2
JM-Phos
R
77
: R = adamantyl
76
R
2
R
2
R
2
R
2
O
O
O
O
N
2
N
2
R
1
(
S
)-
78
:R
1
= Ferrocenyl, R
2
=
i
Pr
(
S
)-
79
:R
1
= Ferrocenyl, R
2
=Bn
(
S
)-
80
:R
1
=3,5-
t
Bu
2
Ph, R
2
=Bn
R
1
(
S
)-
81
:R
1
=Ph,R
2
=Bn
(
S
)-
82
:R
1
=3,5-Me
2
Ph, R
2
=Bn
Figure 7.11.
P,N - ligands.
