Chemistry Reference
In-Depth Information
TABLE 8.14 (continued)
Determination of Pharmaceuticals and Drugs at Carbon Paste Electrodes, Sensors, and Detectors: Survey of Methods and Selected Studies
Analyte
(Chemical
Form)
Classiication (Chem.
Speciication)
Type of CPE (Modiier)/
[Coniguration]
Technique
(Mode)
Experimental and Electroanalytical
Characterization, Selected Data; Notes
Sample(s)
Ref(s)
Acyclovir
.(syn..
Zovirax
)
Synth..antiviral.drug.
(amino-OH-EtO)-Me-1H-
purin-6,9H-one)
C/PO.(+μ-Cu-Ps)
C/PO.(+
n
-Cu-Ps)
CV,.AD
Elec.-catalytic.oxidn..(via.Cu
II
.→.Cu
III
),.
μ-Ps,.
n
-Ps:.micro-.and.nanoparticles,.lin.:.
low.micromolar.level;.RSD.<.5%
comm..products.
(tablets,.topical.
cream)
[961]
Adriamycin
Antitumor.drug.
(anthracycline gr.)
(a).C/Nj.(unm.)
(b).C/PO.(+CTAB,.
in situ
)
(a).CV,.DPV
(b).AdSV
(a).pH.4.5,.LOD:.0.1.μM;.test.EC-LC
(b).3.×.10
−8
-5.×.10
−6
.M,.CTAB:.surf..for.
erosive.activation.of.CP-surface
biol..luids.(human.
urine)
(a).[2499,.
522]
(b).[2501]
Amantadine
Anti-Parkinsonian.ag..
(amino-adamantane)
C/PO.(+
β
-CD)
POT.(dir.)
Inclusion.effect;.CD:.cyclodextrin;.s.e:.
0.02.M.AcB.(pH.4.7),.LOD:.5.×.10
−10
pharm..forms.
(tablets)
[2502]
Ambroxol
.
(hydrochloride)
Bronchosecretolytic.agent.
(cyclohexanol)
C/Nj.(unm.)
CV,.AV
s.e.:.0.5.M.H
2
SO
4
.(pH.0);.4.×.10
−7
-6.×.10
−5
.
M.(LOD:.2.×.10
−7
.M)
Model.solns.
[2503]
Amikacin
Antibioticum.
(aminoglycoside)
C/PO.(+
n
-CuO)
CV,.AD.(stat.)
modif:.nanosized.oxide;.lin..range:.
1-200.mM;.comp..to.the.bare.CPE
pharm..forms.
[1228]
Amikhellin
Antiasthmatic.agent.
(chromone.der.)
C/Nj.(
Metrohm
)
CV
Commercially.available.CP-mixture;.oxidn..
process.studied;.LOD:.1.μM
Model.solns.
[2504]
Amiodarone
Antiarrhythmic.agent.
(benzofuran.diiodo-
phenoxydiamine.der.)
(a).C/Nj.(
Metrohm
)
(b).C/PO.(+
Trit
.,.
in situ
)
(a).CV,.COU
(b).2.5nd.
DeLV
(a).Studies.on.electrode.mechanism.and.
reaction.kinetics,.lin:.5.×.10
−6
-5.×.10
−5
.M
(b).modif.:.
Triton X-100
;.LOD:.0.1.nM
Model.solns.
(a).[2505]
(b).[2506]
Aminophylline
Bronchodilator.(bis-dimethyl-
purine-one.thylendiamine)
C/PO.(+Pt-F)
CV,.DPV
PtE:.electrodeposited.Pt-ilm;.study.on.el..
oxidn.;.s.e.:.BR-B,.AcB,.PhB.(pH.2-8);.
lin.:.μM.level;.GCE.also.tested.
Medical.prod..
(anti-asthma.thigh.
creams)
[2507]
Amitriptyline
.
(hydrochloride)
Antidepressant.(tricyclic.der.)
C/PO.(+PV-N-imidazole)
CV,.DPV
Studies.on.electrode.oxidn..and.pH;.
interfs.;.compared.to.the.bare.CPE
pharms..(dosage.
forms)
[2508]
Amlodipine
.
(besylate)
Antihypertensive.ag..
(dihydropyridine.der)
C/PO.(unm.)
CV,.DPAdSV
Studies.on.el..irrev..oxidn..and.adsorp.;.s.e.:.
pH.11;.lin.r.:1.×.10
−8
-2.×.10
−7
.M
com..drugs.(e.g.,.
Amplopres-A
®
)
[2509]
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