Metal Aryloxides - Alkoxo and Aryloxo Derivatives of Metals - page 544

[Ti(OAr) 2 NCPhCHPhNCH 2 Ph ]
2,5-diaza-1-titanacyclopent-2-ene

OC 6 H 3 Ph 2 -2,6 1.816 (2)

1.829 (2)

162
152

xliv

[Ti(OAr) 2 fBu t NC CH 2 Ph D C CH 2 Ph Nxyg]
xy D 2,6-xylyl folded 2,5-diazacyclopentene ring

OC 6 H 3 Pr i 2 -2,6 1.845 (4)

1.790 (4)

154
174

li

[Ti(OAr) 2 fOC CH 2 Ph D C CH 2 Ph NBu t g]
folded 2-oxa-5-azacyclopentene ring.

OC 6 H 3 Pr i 2 -2,6

1.792 (3)
1.814 (3)

172
171

li

[Ti(OAr) 2 fPhNC CH 2 SiMe 3 D C C CH 2 SiMe 3 D NPh)NPhg]
folded 2,5-diazacyclopentene ring

OC 6 H 3 Ph 2 -2,6 1.856 (7)

1.811 (7)

146
175

li

[fTi(OAr) 2 CH 2 CHMeCMe 2 g 2 2 -O ]
tetrahedral Ti linked by oxo bridge

OC 6 H 3 Ph 2 -2,6 1.793 (3)

1.795 (2)

161
168

xlvi

[Ti OC 6 H 3 Bu t -CMe 2 CH 2 OAr CH 2 SiMe 3 py ]
tbp Ti

OC 6 H 3 Bu t 2 -2,6
OC 6 H 3 Bu t -CMe 2 CH 2

1.850 (4)
1.810 (4)

176
146

lii

[Ti(OAr) 2 2 -Bu t N D CCH 2 Ph CH 2 Ph ]
mono- 2 -iminoacyl

OC 6 H 3 Pr i 2 -2,6

1.816 (3)
1.811 (3)

169
163

liii

[Ti(OAr) 2 2 -PhNDCCH 2 SiMe 3 CH 2 SiMe 3 ]
mono- 2 -iminoacyl

OC 6 H 3 Pr i 2 -2,6 1.850 (4)

1.821 (4)

140
153

liii

xliii J.E. Hill, P.E. Fanwick, and I.P. Rothwell, Organometallics , 9 , 2211 (1990).
xliv J.E. Hill, G. Balaich, P.E. Fanwick, and I.P. Rothwell, Organometallics , 12 , 2911 (1993).
xlv J.E. Hill, P.E. Fanwick, and I.P. Rothwell, Organometallics , 10 , 15 (1991).
xlvi M.G. Thorn, J.E. Hill, S.A. Waratuke, E.S. Johnson, P.E. Fanwick, and I.P. Rothwell, J. Am. Chem. Soc. , 119 , 8630 (1997).
xlvii G.J. Balaich, P.E. Fanwick, and I.P. Rothwell, Organometallics , 13 , 4117 (1994).
xlviii J.E. Hill, G.J. Balaich, P.E. Fanwick, and I.P. Rothwell, Organometallics , 10 , 3428 (1991).
xlix J.E. Hill, P.E. Fanwick, and I.P. Rothwell, Organometallics , 11 , 1771 (1992).
l M.G. Thorn, J.E. Hill, S.A. Waratuke, E.S. Johnson, P.E. Fanwick, and I.P. Rothwell, J. Am. Chem. Soc. , 119 , 8630 (1997).
li L.R. Chamberlain,

L.D. Durfee, P.E. Fanwick, L.M. Kobriger, S.L. Latesky, A.K. McMullen, B.D. Steffey, I.P. Rothwell, K. Folting, and

J.C. Huffman, J. Am. Chem. Soc. , 109 , 6068 (1987).
lii S.L. Latesky, A.K. McMullen, I.P. Rothwell, and J.C. Huffman, J. Am. Chem. Soc. , 107 , 5981 (1985).
liii L.R. Chamberlain, L.D. Durfee, P.E. Fanwick, L. Kobriger, S.L. Latesky, A.K. McMullen, I.P. Rothwell, K. Folting, J.C. Huffman, W.E. Streib,
and R. Wang, J. Am. Chem. Soc. , 109 , 390 (1987).

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