Chemistry Reference
In-Depth Information
Table 6.21
(
Continued
)
Bond length ( A)
Bond angle (
Ž
)
Compound
Aryloxide
M-O
M-O-Ar
Ref.
[Ti(OAr)
2
C
4
Et
4
]
OC
6
H
3
Ph
2
-2,6
1.788 (6)
166
xliii
two independent molecules,
titanacyclopentadiene ring
1.828 (6)
1.804 (6)
1.806 (6)
145
156
176
xliv
[Ti(OAr)
2
CH
2
4
]
two independent molecules,
titanacyclopentane ring
OC
6
H
3
Ph
2
-2,6
1.804 (1)
1.804 (1)
1.817 (1)
1.799 (1)
156
159
151
158
xlv, xlvi
[Ti(OAr)
2
CHPhCH
2
CH
2
CHPh
]
2,5-diphenyl-titanacyclopentane
OC
6
H
3
Ph
2
-2,6
1.801 (3)
1.804 (3)
149
161
xlvi
[Ti(OAr)
2
fCH
2
CH
C
4
H
8
CHCH
2
g]
OC
6
HPh
4
-2,3,5,6
1.802 (3)
149
xlvi
OC
6
H
3
Pr
i
2
-2,6
[Ti(OAr)
2
fC
SiMe
2
Ph
2
C
6
H
8
C
PMe
3
g]
titanacyclopentene ring
1.830 (6)
1.861 (6)
164
159
xlvii
[Ti(OAr)
2
4
-CH
2
CMeCMeCH
2
]
-bound 2,3-dimethylbutadiene
OC
6
H
3
Ph
2
-2,6
1.804 (2)
1.843 (2)
1.843 (2)
151
144
144
xlviii
[Ti(OAr)
2
2
-C
2
H
4
PMe
3
]
pseudo-tetrahedral Ti
OC
6
H
3
Ph
2
-2,6
1.835 (1)
1.838 (1)
161
161
xlix, l
[Ti(OAr)
2
2
-Ph
2
CO
PMe
3
]
pseudo-tetrahedral Ti
OC
6
H
3
Ph
2
-2,6
1.817 (5)
1.839 (5)
159
168
xlix, l
[
ArO
2
Ti
2
-
2
-NCMe
2
Ti(OAr)
2
]
OC
6
H
3
Ph
2
-2,6
1.819 (4)
1.799 (4)
173
160
xliv
[
ArO
2
Ti
C
4
Et
4
CPh
2
O
]
3,4,5,6-tetraethyl-7,7-diphenyl-1-oxa-2-titanacyclohepta-
3,5-diene ring
OC
6
H
3
Ph
2
-2,6
1.804 (1)
1.814 (1)
163
161
xliv
