Chemistry Reference
In-Depth Information
Compound
Aryloxide
M-O
Ref.
[(dicyclohexano-18-crown-6)Na(OAr)].HOAr
7-coord. Na, OAr hydrogen bonded to HOAr
OC
6
H
5
2.363 (4)
xi
[
15-crown-5
2
Na
4
2
-OAr
4
]
4- and 6-coord. Na
2
-OC
6
H
5
2.192 (4) - 2.250 (4)
xii
[(cyclohexano-15-crown-5)
2
Na
4
2
-OAr
4
]
4- and 6-coord. Na
2
-OC
6
H
5
,
3
-OC
6
H
5
2.191 (5) - 2.377 (5)
xii
[(dibenzo-24-crown-8)Na
2
2
-OAr
2
]
planar Na
2
O
2
ring, 6-coord. Na
2
-OC
6
H
4
NO
2
-2
2.296 (4), 2.399 (4)
xiii
[(benzo-15-crown-5)Na(OAr)]
7-coord. Na
OC
6
H
2
NO
2
3
-2,4,6
2.350 (3)
xiv
[(valinomycin)Na(OAr)(OH
2
)]
OC
6
H
2
NO
2
3
-2,4,6
2.37 (2)
xv
[Na(OAr)
OH
2
]
n
8-coord. Na
2
-OC
6
H
2
NO
2
3
-2,4,6
2.326 (3)
xvi
[Na
2
2
-OAr
2
]
5-coord. Na
MeO
CH
2
2
C
6
H
4
NHf
CH
2
2
OMegNC
6
H
4
O-2
2.21 (1), 2.27 (1)
xvii
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vi
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vii
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viii
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ix
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x
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xi
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xii
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xiii
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xiv
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84
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xv
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104
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xvi
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xvii
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