Chemistry Reference
In-Depth Information
Compound
Aryloxide
M-O
Ref.
OC
6
H
3
Bu
t
2
-2,6
[
ArO
(DMSO)Na
2
-DMSO
2
Na(DMSO)(OAr)]
unusual structure with bridging DMSO
2.144 (5)
i
[
Na(OAr)]
n
stacked N
2
O
2
rings; held together by intermolecular
Na-OandNa-
-arene bonds
OC
6
H
5
2.328 (6) - 2.264 (1)
ii
[Na
6
4
-OAr
2
3
-OAr
4
THF
6
]
two face-fused cubes, 4- and 5-coord. Na
3
-OC
6
H
5
4
-OC
6
H
5
2.231 (3) - 2.365 (2)
2.318 (3) - 2.405 (2)
ii
[Na
3
-OAr
tmu
]
4
regular cube, 4-coord. Na, tetramethyl urea
3
-OC
6
H
5
2.282 (3) - 2.315 (4)
ii
[Na
6
-OAr
OH
2
3
]
n
phenoxide
-bound to Na and hydrogen bonded to H
2
O ligands.
6
-OC
6
H
5
2.272 (7), 2.343 (7)
iii
[Na
2
-OAr
OH
2
]
n
4-coord. Na
2
-OC
6
H
5
2.272 (3), 2.340 (4)
iii
[Na
3
-O-
6
-Ar
]
n
each Na bound to 3 O-atoms and
-bound to a phenoxide ring
3
-
6
-OC
6
H
4
Me-4
2.231 (4) - 2.346 (4)
iv
[Na
3
-OAr
DME
]
4
regular cube, 5-coord. Na
3
-OC
6
H
4
Me-4
2.281 (4) - 2.332 (4)
iv
[Na
3
-OAr
nmc
]
4
regular cube, 4-coord Na,
N
-methyl-caprolactam
3
-OC
6
H
5
2.294 (8), 2.298 (7)
v
[Na
3
-OAr
]
4
Na
4
O
4
regular cube, 5-coord. Na
3
-OC
6
H
2
CH
2
NMe
2
2
-2,6-Me-4
2.325 (4) - 2.417 (2)
vi
[Na
6
4
-OAr
2
3
-OAr
4
]
two face-fused cubes, 4- and 5-coord. Na
3
-OC
6
H
4
CH
2
NMe
2
2
-2
4
-OC
6
H
4
CH
2
NMe
2
2
-2
2.234 (5) - 2.344 (5)
2.325 (5) - 2.478 (5)
vii
[
HOAr
Na
2
-OAr
2
Na(HOAr)]
5-coord. Na
2
-OC
6
H
2
CH
2
NMe
2
2
-2,6-Me-4
2.216 (3) - 2.289 (3)
vii
[Na
4
di-
3
-OAr
2
DME
2
]
regular cube, 5-coord. Na
3
-OC
6
H
4
CHDN-2]
2
(C
6
H
4
)
2.25 (1) - 2.39 (1)
viii
[Na
2
-OAr
THF
2
]
2
planar Na
2
O
2
ring, 4-coord. Na
2
-OC
6
H
2
CF
3
3
-2,4,6
2.306 (6), 2.313 (6)
ix
[(dicyclohexano-18-crown-6)
2
Na
4
2
-OAr
4
]
4- and 7-coord. Na
2
-OC
6
H
5
2.213 (2) - 2.323 (2)
x
(
continued overleaf
)
