Chemistry Reference
In-Depth Information
[
Me
2
NH
2
C
fAl
OSiMe
3
4
g
]
4
1.733 - 1.780 (5)
-
133.8 - 143.0
65
av. 1.752
av. 137
[Al
2
-OSiMe
3
2
OSiMe
3
4
]
4
1.667, 1.678 (5)
1.813 (4)
174.3, 159.4 (t)
65
av. 1.672
[
acac
2
Al
-OSiMe
3
2
Al
OSiMe
3
2
]
4 and 6
1.700 (8)
1.788 (6)
169.2 (t)
64
129.6, 132.8 (t)
[Al
OSiPh
3
2
acac
]
4
1.680, 1.700 (4)
-
165.2, 143.3 (t)
64
[GaHf
OC
2
H
4
2
NMeg]
2
5
av. 1.847 (2)
av. 1.960 (8) and 2.018 (2)
115.9 (t, av.)
66
117.9 and 125.2 (b, av.)
[Ga
2
H
4
-OC
2
H
4
NMe
2
2
]
5
-
1.911 (3) and 2.053 (3)
123.0 and 131.3
67
[Ga
2
Me
4
-OC
2
H
4
NMe
2
2
]
5
-
1.913 (3) and 2.078 (3)
124.8 and 129.8
67
[Ga
2
Me
4
f
-OCH
2
C
5
NH
4
g
2
]
5
-
1.925 (3) and 2.073 (3)
125.0 and 128.5
68
[Ga
2
Bu
t
4
-OBu
t
2
]
4
-
1.990 (2) and 1.989 (2)
127.6 and 128.3
69
[Ga
-OCPh
3
Bu
t
2
]
3
1.831 (4)
-
127.5
70
[Ga
2
-OCH
2
SiMe
3
2
CH
2
SiMe
3
4
]
4
-
1.953 - 1.976 (3)
av. 118.8 and 122.4
71
av. 1.967
[Ga
2
-OBu
t
2
H
4
]
4
-
1.902 and 1.908 (9)
129.2
62
av. 1.905
[Ga
2
-OBu
t
2
OBu
t
2
H
2
]
4
-
1.904 and 1.907 (4)
128.4 and 129.2
62
av. 1.905
In
2
-OEt
2
Bu
t
4
]
4
-
2.147, 2.165 (5)
131.0
72
av. 2.156
[In
2
-OCH
2
SiMe
3
2
CH
2
SiMe
3
4
]
4
-
2.163 - 2.182 (2)
av. 125.6 and 131.4
71
av. 2.173
[Tl
4
3
-OCH
2
CF
3
4
]
3
-
2.464 - 2.567 (15)
106.0 - 128.8
72
av. 2.518
av. 116.2
tbp D trigonal bipyramidal, tet D tetrahedral, oct D octahedral; b D bridging, t D terminal.
