Chemistry Reference
In-Depth Information
M-O Bond lengths ( A)
Bond angles (
Ž
)
Metal
MOC
Compound
coordination
Terminal
Bridging
Reference
[Al
4
-OPr
i
6
OPr
i
6
]
4 and 6
av. 1.71 (2)
1.94 (1) (oct)
146 (t, av.)
53
1.80 (2) (tet)
129 (b, av.)
[Al
4
-OPr
i
6
OPr
i
6
]
4 and 6
av. 1.700 (5)
1.925 (5) (oct)
140 (t, av.)
55
1.802 (5) (tet)
129 (b, av.)
[Al
3
Cl
5
-OPr
i
4
]
4 and 5
-
1.917, 1.804 (7) (tbp)
128 (b)
56
1.801, 1.756 (5) (tet)
[
C
6
H
11
NH
3
C
fAl
OPr
i
4
g
]
4
av. 1.74 (1)
-
av. 126
58
[Al
2
-OBu
t
2
OBu
t
4
]
4
1.698 - 1.681 (3)
1.831 - 1.824 (3)
144 (t, av.)
59
av. 1.688
av. 1.828
130 (b, av.)
[Al
2
-NMe
2
-OBu
t
OBu
t
4
]
4
1.671 - 1.697 (4)
1.819 and 1.823 (3)
-
60
av. 1.683
av. 1.821
[Al
OBu
t
3
Me
2
NH
]
4
1.699 - 1.744 (2)
-
-
60
av. 1.718
[Al
2
-l-mentholate
2
Me
4
]
4
-
1.835 - 1.847 (3)
-
61
av. 1.841
[Al
2
-l-mentholate
2
Bu
i
4
]
4
-
1.833 - 1.852 (9)
-
61
av. 1.841
[Al
2
-l-borneolate
2
Me
4
]
4
-
1.829 - 1.861 (5)
-
61
av. 1.841
[Al
2
-OBu
t
2
H
4
]
4
-
1.810 and 1.815 (3)
129.6 and 131.4
62
av. 1.812
[Al
2
-OBu
t
2
OBu
t
2
H
2
]
4
1.675 (3)
1.817 (3)
144.3 (t)
62
130.1 (b, av.)
[
Bu
t
O
2
Bu
t
O
Al
-OBu
t
2
Al(mesal)
2
]
4 and 6
1.69 (1)
Not reported
Not reported
63
mesal D methylsalicylate
[Al
3
-OPr
i
4
OPr
i
2
acac
3
]
4 and 6
1.662, 1.716 (7)
av. 1.909 (7) (oct)
140 (t, av.)
64
1.766, 1.794 (6) (tet)
129 (b, av.)
