Pesticide Residues in Surface Water and Groundwater - Pesticides: Evaluation of Environmental Pollution - page 280

TABLE 9.8
Overview of Methods Reported for the Water Analysis of Pesticides Using Liquid Chromatography

Liquid Chromatography

Sample
Preparation

LOD
(ng/L) Pesticides Samples Column Mobile Phase Detector References

12, triazines + their
metabolites

SW SPE (propazine-

MIP, LiChrolut
EN)

Spherisorb S5 ODS2
(250 × 40 mm i.d. and 5 μm
particle size)

Water (5 mM phosphate
buffer), ACN

PDA 30-100 Carabias-

Martínez
et al. (2005)

14, multiclass SW, GW SPE (Oasis HLB) Zorbax Eclipse® XDB-C18

(75 × 4.6 mm i.d. and 3.5 μm
particle size)

Water (0.1% HAc), MeOH ESI-IT 0.4-5.5 Dujaković

et al. (2010)

31, multiclass SW SPE (Oasis HLB) Acquity BEH C18

(100 × 2.1 mm i.d. and
1.7 μm particle size)

Water (0.1% HCOOH),
ACN

ESI-QqQ 3-20 Gervais et al.

(2008)

9, multiclass GW SPE (Oasis HLB) Acquity BEH C18

(100 × 2.1 mm i.d. and
1.7 μm particle size)

Water (0.1% HCOOH),
ACN

ESI-QqQ 0.1-20 Mezcua et al.

(2006)

7, multiclass Spiked

samples

LLE (EtAc)
SPE (Oasis HLB)

Phenomenex aqua
(150 × 3 mm)

Water (0.1% HAc)-MeOH
(0.1% HAc)

ESI-QqQ <50 Liu et al. (2006)

101, multiclass SW SPE (Sep-pak C18) Zorbax Eclipse XDB-C8

(150 × 4.6 mm i.d. and 5 μm
particle size)

Water (0.1 % HCOOH),
ACN

ESI-TOF — Ferrer and

Thurman
(2007)

12, multiclass SW, GW,

WW

SPE (Strata-C18) Uptisphere C 18 3HDO

(100 × 2.0 mm i.d and 3 μm
particle size)

Water (10 mM aqueous
NH 4 Ac), MeOH

ESI-QqQ 0.2-88.9 Baugros et al.

(2008)

14, multiclass SW, GW,

DW

SPE (Oasis HLB) Atlantis dC18 (150 × 2 mm

i.d. and 5 μm particle size)

Water/MeOH (5 mM
NH 4 Ac)

ESI-QqQ 4.1-43.0 Rodrigues

et al. (2007)

6, quaternary
ammonium

DW On-line SPE

(Hysphere Resin
GP)

Kromasil C8
(200 × 2.1 mm i.d. and 5 μm
particle size)

Water (100 mM formic
buffer + 20 mM HFBA),
ACN

TIS-QqQ
ESI-Q-
TOF

0.1-2
3-20

Núňez et al.
(2004)