Chemistry Reference
In-Depth Information
8
Recent Adventures with the
Pauson-Khand Reaction in
Total Synthesis
Scott G. Van Ornum,
∗
Sarah Hoerner, and James M. Cook
8.1
Introduction
212
8.2
(
+
)-Epoxydictymene
212
8.3
(
±
)-Pentalenene and (-)-Pentalenene
214
8.4
The Tandem Pauson-Khand Reaction Directed Towards the Synthesis of
Dicyclopentapentalenes
215
8.5
Enantioselective Total Synthesis of (-)-
α
-Kainic Acid
219
8.6
The Total Synthesis of Paecilomycine A
220
8.7
The Total Synthesis of (
+
)-Achalensolide
221
8.8
The Total Synthesis of (-)-Alstonerine
222
±
α
8.9
The Total Synthesis of (
)-8
-Hydroxystreptazolone
224
±
α
β
8.10 The Formal Total Synthesis of (
)-
- and
-Cedrene
226
8.11 Additional Applications of the Pauson-Khand Reaction in Total Synthesis
227
8.12 Conclusions
230
Acknowledgements
231
References
231
