Civil Engineering Reference
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(e)
(a)
O
C
O
C
O
C
O
C
O
C
O
C
O
C
O
C
NH 2
(b)
NH 2
(c)
HO 3 S
SO 3 H
NN
NN
NN
HO
SO 3 H
NH 2
(d)
SO 3 H
O
NH
H
H
4
16.14 Functionalization of the CNT membrane via coupling chemistry between amine groups (circled) of the
functional molecule and the carboxylic acid with (a) short (C9)-chain amine, (b) long (C22)-chain amine,
(c) charged dye molecule with SO 3 2 groups, and (d) long-chain polypeptide resulting in change of transport
properties through the CNT membrane (e). Figures (a)-(e) adapted with permission from Majumder et al. , (2005a).
These experiments indicate the feasibility of functionalizing CNT membranes and should offer avenues for
imparting antifouling, biocompatible, molecular recognition or selective adsorption properties, whenever desired.
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