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(a)
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Days
(b)
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Figure 4.3. The percent change in fluorescence intensity of four freshwater samples over 90 days of
storage via refrigeration (4°C) in the dark; horizontal dashed black lines represent analytical repro-
ducibility. (a) Fulvic-like fluorophore (typical excitation maxima 310-370 nm and emission maxima
410-460 nm). (b) Protein-like fluorophore (tryptophan-like fluorophore; typical excitation maxima
270-280 nm and emission maxima 335-360 nm). Black circles, solid black lines = peatland river
(DOC = 14.6 mg/L); dark gray squares, dashed black lines = organic-rich river (DOC = 9.8 mg L -1 );
light gray triangles, dash-dot black lines = agricultural river (DOC = 4.8 mg L -1 ); white diamonds,
dot black lines = urban river (DOC = 3.2 mg L -1 ).
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