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z
y
x
(a)
10 0
10 0
1/2
ϕ
shear modulus
shear modulus
N /
µ sk /
µ S
µ S
10 1
k sk /k S
K b / k S
bulk modulus
bulk modulus
10 2
2
10 1
ϕ
bulk viscosity
ξ sk /
η cc
bulk viscosity
ξ / η cc
10 3
η sk / η cc
η cc
shear viscosity
η
/
shear viscosity
1/2
ϕ =
1-2.3
φ
10 4
10 2
10 2
10 1
10 0
0
0.1
0.15
0.05
Contiguity, ϕ
Melt fraction,
φ
(b)
(c)
Fig. 3.6 The elastic and viscous properties of a solid framework, calculated for a tetrakaidekahedral grain model
with 14 circular contact faces (Figure 3.6a), are shown as functions of contiguity
φ
(Figure 3.6c). The results in (c) are obtained from those in (b) by assuming an equilibrium melt geometry and hence
assuming the
ϕ
(Figure 3.6b) and melt fraction
1
/
2 . The definitions of k sk ,
ϕ
-
φ
relationship given by
ϕ =
1
2
.
3
φ
µ sk ,
ξ sk ,and
η sk and those of
K b , N ,
ξ
,and
η
are given in Equations (3.9) and (3.10), respectively.
η sk approaches the intrinsic viscosity of a solid,
which is
infinitely high dissolution/precipitation reaction
rate. If these factors are finite, and if the melt frac-
tion is smaller than a critical value
(incompressible) for the bulk viscos-
η cc for the shear viscosity. This singular
behavior of viscosity at
φ c , the rate-
limiting process changes from diffusion through
the grain boundaries to dissolution/precipitation
reaction for
ity and
1 can be understood
intuitively (Figure 3.7); even at a very small melt
fraction, the connected network of melt works
as a fast diffusion pathway and significantly de-
creases viscosity as a result of the short-circuit
effect. Equations (3.16) implicitly assume a liquid
diffusivity that is infinitely high as well as an
ϕ
ξ sk and to diffusion though the liquid
for
η sk deviate from the val-
ues shown in Figure 3.6b and rapidly approach
η sk .At
φ<φ c ,
ξ sk and
and
η cc , respectively (Takei & Holtzman, 2009b).
Therefore, the ''mathematical singularity'' can
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