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most debated and recent questions and the key information that may be
derived from ground-based observations, on Mercury's exosphere — magne-
tosphere — upper surface system. Such information is particularly needed
in preparation of the forthcoming Messenger and BepiColombo missions.
In Sec. 2, we give a brief overview of the known neutral and ion compo-
sitions of Mercury's exosphere. Section 3 describes some important sources
of variations of the exospheric abundance related to the coupling between
Mercury's exosphere, its upper surface, and its magnetosphere. Section 4
concludes this paper.
2. Exospheric Composition
The only few elements that Mariner-10 provided on Mercury's neutral exo-
sphere are:
(i) the measurements of H and He with surface density of 250 H/cm 3 and
6
10 3 He/cm 3 , 11
(ii) an identification of O column density with suggested value for its sur-
face density of 4 . 4
×
10 4 O/cm 3 , 12 , 13
(iii) an upper limit for the total content of the exosphere at the subso-
lar point: 10 7
×
neutral particles/cm 3
from the solar occultation UV
measurement. 12
Ground-based observations identified:
(i) Na atoms with zenith sub-solar column density of 10 11 Na/cm 2 , 4 , 14
(ii) K atoms with column density of 10 9 K/cm 2 , 4 , 15 , 16
(iii) Ca atoms with column density of 10 8 Ca/cm 2 . 17
Only upper limits are known for other elements from Mariner-10 solar
occultation UV experiment: at the surface density 1 . 4
10 7 H 2 /cm 3 ,2 . 5
×
×
10 7 O 2 /cm 3 ,2 . 3
10 7 N 2 /cm 3 ,1 . 5
10 7 H 2 O/cm 3 ,1 . 6
10 7 CO 2 /cm 3 and
×
×
×
10 7 Ar/cm 3 . 12 Hunten et al. 11 suggested that densities of 10 4 H 2 /cm 3 ,
1H 2 O/cm 3 ,and1CH 4 /cm 3 are more realistic for these species (for H 2 O
and CH 4 in particular because of a short-lifetime against photoionization).
At the Moon, which is the best analog of Mercury's exosphere, O 2 has
never been measured, N 2 has been measured with 8
3 . 1
×
10 2 N 2 /cm 3 ,CO 2
×
with 10 3 CO 2 /cm 3
10 4
to 10 5 Ar/cm 3 . 18 Upper imitsattheMoonforO,N,C,Fe,andS
below 10 3 particles/cm 3 ,SiandAlbelow10 2 particles/cm 3 have also been
reported. 18
(the same density as for CO), and Ar with 4
×
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