Chemistry Reference
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Fig. 4.16 a
Schematic representation of the synthesis of MCOF-1;
b
Argon adsorption and des-
orption (
open symbols
) isotherm of MCOF-1 measured at 87 K.
Inset
Pore size distribution cal-
culated by the NLDFT model
different polarizability. The fast dynamic breakthrough tests further proved that
the ZnP-CTF-400 and ZnP-CTF-500 could separate small hydrocarbons based on
their hierarchical isosteric heats in an actual adsorption-based separation process
(Fig.
4.15
).
We have also successfully synthesized a new microporous crystalline mate-
rial (MCOF-1) with narrow pore size distribution of 0.64 nm (Fig.
4.16
) [
69
].
MCOF-1 possessed architectural stability and porosity after evacuating solvent
molecules. Additionally, MCOF-1 showed high adsorption capacity for C
2
H
4
,
C
2
H
6,
and C
3
H
8
. At 298 K and 1 bar, the uptake of MCOF-1 is 9, 36, 44 and
