Chemistry Reference
In-Depth Information
Fig. 6.20
Synthesis of PFeTTPP.
a
Molecular structure;
b
simulated 3D stacking of PFeTTPP.
Fe
red
, N
blue
, C
light
blue
, S
yellow
; H not shown for clarity. Reprinted with permission from
Ref. [
48
]. Copyright 2013, Wiley-VCH
COP-P. But the resulting material showed no catalytic activity. It was resulted
from the poor solubility of the synthesized COP materials in most common
solvents.
Such a template-free approach toward porous carbons with controlled integra-
tion of metal nanoparticles and unique structural features opens up new avenues to
nanostructured carbon materials for fuel cells, batteries, and supercapacitors.
Indeed, POFs have displayed a great deal of excellent performances thanks to
their self-characteristics, including high surface area, high stability, tuned pore
size, and various structures, etc. Via creative exploration, the unexpected proper-
ties of POFs could be discovered.