Chemistry Reference
In-Depth Information
The unimportant role of the kinetic factors is explained by the fact that they
only influence
T
III
S
, which contributes insignificantly to the total gasification heat
H
+
c
s
(
T
II
S
−
Q
Σ
=
Δ
T
∞
), where
Δ
H
is the thermal effect of high-temperature de-
composition and
c
s
(
T
II
S
−
T
∞
) is the heat of warming-up.
The degree of reliability of this conclusion is of special interest when attempting
to understand the mechanism of polymer burning and when developing methods for
increasing the rate of burning in hybrid rocket engines.
The value of
Q
Σ
cannot be theoretically estimated at present due to a lack of
data on high-temperature linear pyrolysis product composition for most practically
important polymeric fuels. The next chapter is devoted to methods for the experi-
mental determination of
Q
Σ
as well as the verification of the ideas discussed in this
chapter.
References
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