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initial NO 2 concentration, accompanied by a small drop in the NO 2 removal
efficiency.
Fig. 4.10 NO 2 removal efficiency at different initial concentrations with the existence of S(IV)
(ppm)
4.5 Simultaneous Removal of SO 2 and NO 2
Obviously, the SO 2 absorption in the liquid phase mostly leads to an increase in
the tetravalent-S concentration and a decrease in the pH value. Meanwhile, the
NO 2 absorption behavior lowers both the pH value and tetravalent-S concentration.
The interactions between SO 2 and NO 2 must be clearly understood so as to
increase the simultaneous removal efficiencies of multi-pollutants.
4.5.1 Effect of SO 2 on NO 2 Removal
In the related experiments, the pH value and tetravalent-S concentration was kept
at 5.5 and 0.01 mol/L, respectively, while the SO 2 concentration was adjusted
within 0 - 500 ppm to form a series of test settings. As shown in Fig. 4.11, results
suggest that the SO 2 effect on the NO 2 removal efficiency is negligible. That is,
the removal efficiency slightly decreases from 70% to 67% as the SO 2
concentration increases in 0 - 500 ppm. This observation occurs because of the
dual roles of the SO 2 absorption: (i) promoting the reactions listed in Eqs. (4.10)
and (4.11) by increasing the tetravalent-S concentration; (ii) decreasing the pH
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