Civil Engineering Reference
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40
CEM I
CEM III > 50% slag
30
CEM I, 18 -30% fly ash
Fly ash, extrapolated
20
10
0
0.30
0.35
0.40
0.45
0.50
0.55
0.60
0.65
w/b
Figure 15.2 Correlation between w/b and D RCM at about 28 days; all values* 10 -12
m 2 /s.
15.3.2 Modelling chloride ingress
In the DuraCrete model, the evolution of chloride profiles is approximated
with:
x
C
(
x
,
t
)
=
C
(
C
C
)
erf
}
(15.2)
s
s
i
{
4
k
D
(
t
)
t
where C ( x , t ) is the chloride content (all chloride contents in this chapter
are expressed in percentage by mass of binder) at depth x at time t , C s is the
surface chloride content, C i the initial chloride content of the concrete, k is
a correction factor, D ( t ) is the apparent diffusion coefficient as a function of
time (see below) and t is time. The surface chloride content was assumed to be
independent of mix composition for reasons of simplicity: 3.0% for marine
structures (Polder and Rooij, 2005; Rooij and Polder, 2005) and 1.5% for
land-based structures (exposed to de-icing salts), based on data from (Gaal et
al., 2003). The initial chloride content was taken equal to 0.1%.
The apparent diffusion coefficient D ( t ) is multiplied by a correction
factor k to obtain the chloride diffusivity of concrete in a real structure. This
correction factor depends on binder type, environment and length of wet
curing. Some of the deviations from pure diffusion behaviour are included
in this parameter. The k -values were taken from DuraCrete or interpolated
(Duracrete, 2000). The critical chloride content was taken to be equal to
 
 
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