Agriculture Reference
In-Depth Information
MEP pathway
all- trans - -carotene
IPP
OH
all- trans -zeaxanthin
HO
VDE
ZEP
OH
all- trans -antheraxanthin
O
HO
VDE
ZEP
OH
HO
all- trans -violaxanthin
O
HO
OH
NSY
HO
Isomerase?
O
HO
all- trans -neoxanthin
Isomerase?
O
O
HO
HO
9- cis -violaxanthin
9 - cis -neoxanthin
NSY?
O
HO
OH
OH
NCED
NCED
Plastid
Cytosol
Xan
O
CHO
HO
XD
ABAld
OH
O
COOH
CHO
HO
O
Xanthoxic acid
ABAO
MOSU
OH
CH 2 OH
O
Abscisic alcohol
OH
ABA
COOH
O
Fig. 2.2 ABA biosynthetic pathway in higher plants. The ABA precursor, a C40 carotenoid, is
synthesized from IPP originating from the MEP pathway. Solid arrows indicate one-step modi-
fication of an intermediate and dashed arrows represent multistep modifications of an interme-
diate. Enzyme names are given in bold . Abbreviations: IPP isopentenyl pyrophosphate, ZEP
zeaxanthin epoxidase, VDE violaxanthin de-epoxidase, NSY neoxanthin synthase, NCED 9- cis -
epoxycarotenoid dioxygenase, XD xanthoxin dehydrogenase, ABAO abscisic aldehyde oxidase,
MOSU MoCo sulfurase, Xan xanthoxin, ABAld abscisic aldehyde
 
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