Environmental Engineering Reference
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(a)
(b)
Figure 6.3 (a) Open-path FTIR sensing of the gas composition at Yasur volcano
(Vanuatu) during (b) ash-rich explosive activity (courtesy of P. Allard; data from
Allard et al ., 2012 ). A black and white version of this
figure will appear in some
formats. For the colour version, please refer to the plate section .
illustrates the Multi-GAS results obtained during
field surveys at several
arc, hot-spot and rift-related volcanoes. Multi-GAS-based volcanic arc gas
compositions appear to span a far more restricted range than direct sampling
results would suggest ( Figure 6.2 ), with an apparent cluster of gas samples
at CO 2 /S ratios of
~
2.0 0.5 (mean standard deviation) and H 2 O/CO 2
ratios of
35 10. The implications of this observation are further discussed
in Section 6.4.2 .
The main contribution of the Multi-GAS to volcanology is the demonstration
that fully automated systems can be deployed to make continuous, unattended,
near-real-time
~
field measurements of the compositions of gas plumes (Aiuppa
et al ., 2007 , 2009 , 2010 ; Shinohara, 2013 ). Permanent Multi-GAS observations
have targeted measurements of CO 2 /SO 2 ratios of volcanic-gas plumes. Numerical
simulations of volcanic degassing suggest that high CO 2 /SO 2 ratios can be used to
track pre-eruptive degassing of more primitive (gas-rich) magma (Aiuppa et al .,
2007 ). Continuing improvements in the temporal resolution of Multi-GAS instru-
mentation networks have allowed precursor cyclic changes in the volcanic-gas
CO 2 /SO 2 ratio to be systematically detected prior to basaltic eruptions ( Figure 6.5 )
(Aiuppa et al ., 2009 , 2010 ).
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