Biology Reference
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Fig. 12.13 A comparison between a molecular spectrum and an “RNA spectrum” (or “ribonic
spectrum”). (a) The Raman spectrum of PCl 4 VOCl 4 (tetrachlorophosphonium oxotetrachloro-
vanadate) indicates the probability of the vibrational transitions within the molecule as a function
of the vibrational energies expressed in the units of wavenumbers (Reproduced from Rold´n et al.
2004). (b) An example of the “ribonic spectrum” indicating the probability of observing various
RNA trajectories (ribons) represented by node numbers
the transitions among the electronic, vibrational, and/or rotational levels within
molecules. In contrast, the y -axis of RNA spectrum measures the number of RNA
molecules whose trajectories have similar shapes, regardless of the underlying causes .
In other words, molecular spectroscopy deals with dynamics , and RNA spectroscopy
(or “ribonoscopy”) is concerned with kinematics (see Row 8, Table 12.5 ), the two
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