Civil Engineering Reference
In-Depth Information
TABLE 16-3. Advantages and Disadvantages of Oxidants Used in Water Treatment
Oxidant
Advantages
Disadvantages
Chlorine
Strong oxidant
Reacts with naturally occurring organics and inorgancs in
water to form undesirable DBPs
Economical
Versatile
Hazards associated with using chlorine gas
Simple operation
May cause taste and odor problems
Provides persistent residual that is easy to measure and
control
Extensive track record of successful use
Chloramines
No THM formation
Weak oxidant
Relatively simple operation
May lead to nitrification problems in distribution system
Provides persistent residual
Produces TOX
Extensive track record of successful use
Chlorine Dioxide
Strong oxidant
Relatively high cost
Versatile
Must be generated on-site
Does not produce halogenated DBPs (unless chlorine
present as impurity)
Produces chlorite, a regulated DBP
Difficult to maintain a residual
Does not react with ammonia
May produce undesirable odors
Residual may be stripped by aeration
May produce biodegradable organic material that must be
controlled
Potassium Permanganate
Simple operation
Only moderately strong oxidant
Does not produce halogenated DBPs
High chemical cost
Slow reaction time for some applications
Can lead to pink water if dosage not carefully controlled
Produces manganese dioxide which must be removed
Does not provide a persistent residual
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