Chemistry Reference
In-Depth Information
7.5 In octahedral symmetry the fictitious
S
operator follows the
T
1
irrep. Its third
symmetrized power transforms as the components of the
f
-harmonics and also
subduces a
T
1
irrep, as indicated in Table
7.1
. Rewrite the
p
- and
f
-parts of
the
|
T
i
|
operators for the
Γ
8
quartet state as a spin Hamiltonian of the fictitious
spin.
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