Environmental Engineering Reference
In-Depth Information
Then the total derivative of the enthalpy can be expressed as
H
dH
M
o
T
þ l
0
T
o
ð
;
Þ
¼
ð
5
:
53
Þ
dh
s
H
c
H
dT
M
The speci
c heat c
H
in this case represents the speci
c heat in a constant
magnetic
eld for the magnetic
fl
uid. This means that is takes into account both, the
speci
c heat of the base or carrier
liquid. The magnetocaloric material in a static magnetic
c heat of the magnetic material and the speci
eld exhibits a phase
change in the form of latent heat. In such a case, it is more convenient to keep the
energy equation in a form with the enthalpy (i.e. Eq.
5.49
).
The enthalpy of the magnetic
fl
uid (at a constant magnetic
eld) may be de
ned
as follows:
m
solid
h
solid
þ
m
liquid
h
iiquid
h ¼
¼
/
m
h
solid
þ
1
/
m
ð
Þ
h
liquid
ð
5
:
54
Þ
m
If the liquid phase does not undergo a phase change, then Eq. (
5.54
) may be
written as
m
solid
h
solid
þ
m
liquid
c
p liquid
#
liquid
m
h
¼
¼
/
m
h
solid
þ
ð
1
/
m
Þ
c
p liquid
#
liquid
ð
5
:
55
Þ
In this case, a special continuous-properties model can be applied, given by
Egolf and Mantz [
96
]. The contributions of the magnetic
eld change can be added
to such a model.
In the subsequent text we apply equations that consider the magnetic material to
possess ordinary speci
c heat properties. For this particular case, the speci
c heat
c
H
of the magnetic
fl
uid can be calculated using the simple relation (see also Xuan
and Roetzel [
97
]):
m
solid
c
H solid
þ
m
liquid
c
p liquid
c
H
¼
¼
/
m
c
H solid
þ
ð
1
/
m
Þ
c
p liquid
ð
5
:
56
Þ
m
With the help of Eqs. (
5.49
5.53
) the energy equation can be now written as
-
H
DH
h
i
c
H
DT
M
o
Dt
þ l
0
M
DH
Dt
þ l
0
T
o
¼
viscous
:
r~
Dt
¼
r
_
M
q
þ
v
ð
5
:
57
Þ
T
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