Environmental Engineering Reference
In-Depth Information
Table 4.17
Detailed kinetic parameters of 94 reactions and 31 species
A
(cm
3
/(mol·s))
No.
Reactions
E
a
(cal/mol)
Resources
Widmer and West
[3]
1 Hg+Cl+M=HgCl+M
2.40E8
1.4
14400
Widmer and West
[3]
2 Hg+Cl
2
=HgCl+Cl
1.39E14
0.0
34000
Widmer and West
[3]
3 HgCl+Cl
2
=HgCl
2
+Cl
1.39E14
0.0
1000
Widmer and West
[3]
4 HgCl+Cl+M=HgCl
2
+M
2.19E18
0.0
3100
19000 Widmer and West
[3]
5 Hg+HOCl=HgCl+OH
4.27E13
0.0
79300 Widmer and West
[3]
6 Hg+HCl=HgCl+H
4.94E14
0.0
Widmer and West
[3]
7 HgCl+HCl=HgCl
2
+H
4.94E14
0.0
21500
Widmer and West
[3]
8 HgCl+HOCl=HgCl
2
+OH
4.27E13
0.0
1000
9 Hg+NO
3
=HgO+NO
2
2.41E09
0.0
0.0
This work
10 H
2
O
2
+Hg=HgO+H
2
O
5.12E05
0.0
0.0
This work
11 Hg+ O
3
=HgO+O
2
1.8E04
0.0
0.0
This work
12 Hg+OH=HgO+H
7.23E10
0.0
0.0
This work
13 O+Hg=HgO
7.23E10
0.0
0.0
This work
14 Hg+Cl=HgCl
8.37E11
0.0
This work
413
Baulch
et al.
[39]
15 Cl+Cl+M=Cl
2
+M
2.23E14
0.0
1800
Baulch
et al.
[39]
16 H+Cl+M=HCl+M
7.19E21
2.0
0.0
Adusei
et al.
[44]
17 HCl+H=H
2
+Cl
1.69E13
0.0
4133
Baulch
et al.
[39]
18 H+Cl
2
=HCl+Cl
8.59E13
0.0
1172
Mahmud
et al.
[45]
19 O+HCl=OH+Cl
4.26E10
2.87
3517
Ravishankara
et al.
[46]
20 OH+HCl=Cl+H
2
O
3.27E11
1.65
223
Bradley
et al.
[47]
21 O+Cl
2
=ClO+Cl
6.17E12
0.0
3577
Ongstad
et al.
[48]
22 O+ClO=Cl+O
2
1.57E13
0.0
193
Atkinson
et al.
[49]
23 Cl+HO
2
=HCl+O
2
1.08E13
0.0
338
Atkinson
et al.
[49]
24 Cl+HO
2
=OH+ClO
2.47E13
0.0
894
Atkinson
et al.
[50]
25 Cl+H
2
O
2
=HCl+HO
2
12.800
0.0
1947
Atkinson
et al.
[50]
26 ClO+H
2
=HOCl+H
6.03E11
0.0
14100
Adusei
et al.
[51]
27 H+HOCl=HCl+OH
1.69E13
0.0
4133
Wang
et al.
[52]
28 Cl+HOCl=HCl+ClO
4.17E09
4.07
337
Boodaghian
et al.
[53]
29 Cl
2
+OH=Cl+HOCl
1.02E12
0.0
1810
Atkinson
et al.
[40]
30 O+HOCl=OH+ClO
6.03E12
0.0
2583
DeMore
et al.
[54]
31 OH+HOCl=H
2
O+ClO
1.81E12
0.0
994
Atkinson
et al.
[49]
32 HOCl+M=OH+Cl+M
10.250
3.0
56720
Song
et al.
[55]
33 Cl+Cl=Cl
2
2.0E15
0.0
0.0
Leu
et al.
[56]
34 HCl+O
3
=HOCl+O
2
2.83
0.0
0.0
Shaw
[57]
35
H+HO
2
=OH+OH
8.22E12
0.75
0.0
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