Geoscience Reference
In-Depth Information
Compound
Representative
Cell Parameter
( ˚ )
Rare Earth, Co.
No., Average
Bond Distance ˚
Tetrahedral Radical
Form
Rare Earth
Polyhedra
R [PO 4 ]
Y[PO 4 ]
14/and Z 5 4
Y
8
2.28
Orthotetrahedra
Framework
R 5 Gd Lu, Y, Sc
a 5 6.885
c 5 5.982
R [PO 4 ]
Ce[PO 4 ]
P3 1 21 Z 5 3
Ce
8
2.48
Orthotetrahedra
Framework
R 5 La Eu
a 5 7.055
c 5 6.439
R [PO 4 ]
Ce[PO 4 ] monazite
P2 1 /nZ 5 4
Ce
8
2.51
Orthotetrahedra
Framework
R 5 La Dy
a 5 6.78
b 5 7.00
c 5 6.44
β 5 103.63
YbH 2 [P 3 O 10 ]
A 2 Z 5 2
Yb
6
2.19
Triortho groups
Discrete polyhedra
a 5 5.617
b 5 6.666
c 5 10.011
β 5 97.32
R [PO 3 ] 3
Nd [PO 3 ] 3
C222 1 Z 5 4
Nd
8
2.43
Chains with a period
of 6-tetrahedra
Columns
R 5 La Gd
a 5 11.172
b 5 8.533
c 5 7.284
R [PO 3 ] 3
Yb [PO 3 ] 3
P2 1 /cZ 5 12
Yb
6
2.20
Chains with a period
of 6-tetrahedra
Discrete polyhedra
R
Gd
Lu
a 5
11.219
5
b 5
19.983
c 5 9.999
(Continued)
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