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N = 1:4
Pr
Na 2 R 6 [Ge 2 O 7 ] 2 [Ge 4 O 12 ]
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tu
Yb
Lu
Y
NaR[GeO 4 ]
Na 4 R 2 [Ge 4 O 13 ]
NaOH
20%
60%
90%
100%
Figure 7.45 NC diagram for sodium rare earth germinate system: T 5 650 C,
P 5 400 2500 atm [44] .
c
-Na
-Nd
NaNd 3 [GeO 4 ](OH) 2
b
Na 2 Nd[GeO 4 ](OH)
NaNd[GeO 4 ]
C Na 2 O
Figure 7.46 Change in rare earth motif during phase transition [44] .
concentration 5
6 mm size, commonly as
equidimensional crystals with pinacoidal and rhombohedral prisms belonging to the
olivine-type structure, are formed.
NaRGeO 4 crystallizes over a broad field and the GeO 2 /R 2 O 3 5
42 wt% and 100% output. Crystals of 4
2:1
1:1 in the
NaOH solutions of 5
80 wt% with 100% output. Crystals of 5 mm size have been
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