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RB 2 O 3 /SiO 2
4:1
[SiO 4 ]
[SiO 4 ]
1:1
[Si 2 O 7 ]
[Si 6 O 15 ]
[SiO 4 ]
[Si 12 O 36 ]
1:4
[Si 6 O 14 ]
50
C NaOH (wt%)
Figure 4.3 NC diagram for the system Na 2 O a RE 2 O 3 a SiO 2 a H 2 O under hydrothermal
conditions.
1000
900
800
700
600
500
400
300
200
100
0
LaPO 4
LaPO 4
LaP 8 O 9
LaP 3 O 9 ·
KLaP 4 O 12
n
H 2 O
LaP 5 O 14
LaPO 4 · n H 2 O
KLaP 4 O 12 .
n
H 2 O
La 5 (P 3 O 10 ) 3 · n H 2 O
La(OH) 3
KLaHP 3 O 10
K 5 P 3 O 10
0
2
4
pH of the medium
6
8
10
Figure 4.4 TC diagram for the system K 2 O a La 2 O 3 a P 2 O 5 a H 2 O [11] .
diagrams—even in the phase diagrams of crystallization, the components can be
represented, for example, in a ternary system as a triangle. Figure 4.5 shows the
phase diagram of crystallization in the system LiO 2 a
H 2 O at 750 C and
Ta 2 O 5 a
1700 atm [12] .
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