Geoscience Reference
In-Depth Information
The integration limits are introduced by the product of Heaviside's step functions
. u .// . . u .///: We h ave
Z
e u ./ 2 d u
".a/ D . u /
d . u .// . . u .///d;
(3.146)
1
where u ./ is given by Eq. 3.142 , u is the positive zero of this function, and
"
" C 1 S./ # :
4 3
. 2
2 d u
2
" C 1
1
"
d D
1/ 3 C
1/ 2 C
(3.147)
. 2
3.5.5
Charging of Metallic and Small Dielectric Particles
Less general and more observable results can be obtained for metallic particles
" D1 and small dielectric particles a ˇe 2 .
C
3.5.5.1
Neutral Particle
Ion
A neutral particle interacts with ions via image forces whose potential is always
attractive (Q D 0 and D 0 in Eqs. 3.139 , 3.140 , 3.141 , 3.142 , 3.143 , 3.144 ,
3.145 , 3.146 , 3.147 , 3.148 , 3.149 , 3.150 , 3.151 , 3.152 , 3.153 , 3.154 , 3.155 , 3.156 ,
3.157 , 3.158 , 3.159 ).
We begin by considering a metallic particle (" !1 , S./ D 1= 2 2
1 ).
Equation 3.115 reduces to u D 2
1 2 and can be solved analytically to give
1
p u :
2
. u / D 1 C
(3.148)
From Eq. 3.145 we can find :
. . u // D u C 2 p u :
(3.149)
Equation 3.115 immediately leads to the familiar result (Natanson 1960 ):
r ˇq 2 e 2
2a
Z
1 C 1= p u d u D 1 C
e u
".a/ D
:
(3.150)
0
For dielectric particles we must use the general result, Eqs. 3.146 and 3.147 with
D 0. However, some analytical results can be found in the limit of small particles
a ˇe 2 . We will derive a two-term (approximate) formula similar to Eq. 3.148 .
 
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