Geoscience Reference
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0.150
Koolau
Hawaiian volcanoes
0.145
Mauna Loa
0.140
0.135
Mauna Kea
0.130
Upper mantle
0.125
0.120
4.6
4.8
5.0
5.2
5.4
5.6
5.8
6.0
18 O (per mil)
δ
Figure 11.12 Relationship between the 187 Os
18 OoflavasamplesfromthreeHawaiian
volcanoes. The variation in abundance in 18 O means that the source of these lavas contains a
constituent that was processed under low-temperature surface conditions. Isotopic fractionation
of Os requires the presence of a rock source that was once composed of ancient magmatic liquids
and cumulates. The combination of these two characteristics suggests that these basalts
remobilize ancient continental crust buried deep within the mantle. Other criteria preclude
contamination by the present-day lithosphere (after Lassiter and Hauri, 1998 ) .
188 Os ratio and
/
δ
from pelagic sediments (deep-sea clays), with high 176 Lu/ 177 Hf ratios, through the basaltic
part of the weathered basalt crust, with high
18 O and 187 Re/ 188 Os, to cumulate rocks
(gabbro) of the lower oceanic crust with their low
δ
18 O and 187 Re/ 188 Os ( Fig. 11.12 ). It
is becoming ever clearer that the process forming most of the OIB source is recycling of
old oceanic crust, possibly after melting or devolatilization of fluids in the course of plate
subduction.
Overall, our current understanding of the isotope geochemistry of oceanic basalts can
be boiled down to three simple but strong statements: (i) it is created by two independent
groups of processes taking place, one at mid-ocean ridges and the other at subduction
zones; (ii) extraction of continental crust accounts for the overall depleted character of the
mantle; and (iii) the contrast between OIB and MORB cannot be created in a short time
interval, e.g. upon ascent and melting of a particular batch of mantle, but requires multiple
cycles of convection, upwelling, and subduction.
The interpretation of the isotope compositions of the inert gases in the various types of
basalt remains, however, not agreed upon. Typical ridge basalts have 3 He/ 4 He ratios four
times lower than basalt of ocean islands such as Hawaii or Iceland. Let us refer back to
(4.37) , where we show the closed-system evolution of 3 He/ 4 He. We can sketch the evo-
lution of the 3 He/ 4 He ratios in the mantle source of ocean island and mid-ocean ridge
basalts by assuming constant parent/daughter ratios ( Fig. 11.13 ). Helium is distinctly more
radiogenic in MORB than in OIB. The apparent 238 U/ 3 He ratio integrated over the Earth's
history is therefore higher in the MORB source than in the OIB source. Given the much
more volatile character of He compared with U and Th, it is inferred that parts of the OIB
δ
 
 
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