Chemistry Reference
In-Depth Information
Fig. 2.9
Portrait of Johann
Heinrich Lambert
(ca. 1728-1777)
Lambert's topic,
Photometria
[
95
], that deals with optical measurements was
published in 1760. In it, he stated:
If a light beam with an intensity
I
passes through a layer [in his experiments, of glass]
of width
l
, its intensity will decrease to
I
1/n of its original intensity while if it passes
through a further similar layer its intensity will decrease to
I
1/n 1/n of its original
value. For
m
layers the intensity of the exiting light will be
I
′
=
I/n
m
.
He also noted:
The amount of captured light is the greater, the greater the number of particles within a
given volume and the larger the surface area of a given particle.
Later, in 1852, Beer pointed out that the Lambert law also applied to solutions and
defined the absorption coefficient [
96
].
The Beer-Lambert law could equally be described as the Bouguer-Bernard
law. Bouguer's research predated but was unknown to Lambert, his
Essai
[
97
] was
published in 1729. Bernard also defined the absorption coefficient, a few months
after Beer [
98
].
The Demise of Phlogiston and the Rise of Stoichiometry
and Quantitation
Carl Wilhelm S
cheele
(born 19 December 1742, Stralsund; died 21 May 1786,
Köping, Sweden) is normally listed as a Swedish chemist but is included herein
because Stralsund is in Western Pomerania, then a Province of Prussia, although
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