Civil Engineering Reference
In-Depth Information
Because RHA has a high surface area, it acts as a good pozzolan.
A mixture of CH and RHA promotes the formation of a C-S-H product of
composition Ca
1.5
•SiO
3.5
•XH
2
O.
[59]
The TG/DTA curves for the system
RHA-CH mixtures are shown in Fig. 23. The evaporation of water is
denoted by an endotherm at about 140°C. Thereafter, there is a gradual loss
of water and at 827°C crystallization to wollastonite is indicated by an
exothermic peak.
Figure 23.
TG-DTA of the reaction product of RHA and Ca(OH)
2
.
The rate of heat development in RHA cement pastes containing
from 5 to 20% RHA has been followed by Hwang and Wu.
[58]
The shapes
of the curves for all the mixes including the curve for the reference cement
are similar (Fig. 24). The first peak that appears within a few minutes is
lower in all samples containing RHA. The second peak occurring at about
10 hours is lower in samples with RHA-cement pastes. The lower heat
effect is caused by the reaction of K
+
and Ca(OH)
2
with RHA. The dilution
effect also plays a part.
