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by DTA, TG, SEM (EDX), porosimetry, and chemical analysis. TG
showed a loss in weight at 60°C for the loss of adsorbed water, and other
losses occurred due to the dissociation of C-S-H, Mg(OH) 2 , Ca(OH) 2 , and
CaCO 3 . The w/c ratio that was used to make concrete did not influence the
total amount of combined water. Higher amounts of carbonate were found
in concretes made at lower w/c ratios. It was also concluded that the
transition zone contained C-S-H and Ca(OH) 2 , the relative ratios depending
on the type of cement and cement:aggregate: water ratio.
REFERENCES
1.
Ramachandran, V. S ., Applications of Differential Thermal Analysis in
Cement Chemistry, p. 308, Chemical Publication Co., New York (1969)
2.
Ramachandran, V. S., and Garg, S. P., Differential Thermal Analysis as
Applied to Building Science (with an annotated bibliography), p. 182,
Central Building Research Institute, India (1959)
3.
Longuet, P., Application of Thermogravimetry to the Chemistry of Cement,
Rev. Materiaux de Construction, 537:538-540 (1960)
4.
Mackenzie, R. C., (ed.), Differential Thermal Analysis, 2:607, Academic
Press, London (1972)
5.
Ghosh, S. N., (ed.), Advances in Cement Technology, p. 804, Pergamon
Press, London (1983)
6.
Ramachandran, V. S., and Beaudoin, J. J., (eds.), Handbook of Analytical
Techniques in Cement Science and Technology, p. 964, Noyes Publications,
NJ (2001)
7.
Ramachandran, V. S., Elucidation of the Role of Chemical Admixtures in
Hydrating Cements by DTA Technique, Thermochimica Acta, 3:343-366
(1972)
8.
Bhatty, J. I., Review of Application of Thermal Analysis to Cement-
Admixture Systems, Thermochimica Acta, 189:313-350 (1991)
9.
Ramachandran, V. S., Feldman, R. F., and Sereda, P. J., Applications of
Thermal Analysis in Cement Research, Highway Res. Rec., 62:40-61
(1964)
10.
Rowland, R. A., and Beck, C. W., Determination of Small Quantities of
Dolomite by Differential Thermal Analysis, Am. Mineralogist, 37:76-82
(1952)
11.
Ghosh, S. N., and Mathur, V. K., Testing and Quality Control in Cement
Industry, p. 497, Akademia Books Int., New Delhi (1997)
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