Biology Reference
In-Depth Information
interesting feature is that the chirality-organized structure of
3
is
preserved in spite of the complexation with
CA
.
O
NN
Me
H
O
O
NH
N
Me
Me
Me
Me
HOOC
H
Fe
Me
COOH
N
NH
O
CA
O
H
NN
Me
O
Fc(-
L
-Ala-
L
-Pro-NH-2-PyMe)
2
3
Figure 3.5
The ferrocene-peptide bioconjugate
bearing the dipeptide
chains (-L-Ala-L-Pro-NH-2-PyMe) and (1
3
R
,3
S
)-camphoric
acid (
CA
).
(a)
(b)
(c)
Figure 3.6
(a) A portion of a layer containing the double-helical-like
hydrogen-bonded molecular assembly in the crystal packing
of
, (b) space-filling representations of a top view,
and (c) a side view.
3•(CA)
2
Search WWH ::
Custom Search