Chemistry Reference
In-Depth Information
Table 2 Summary of the conclusions of the inherent structure rule for organothiolato-gold cluster
aa
0
mn
bcd sx
Icosahedra based
[Au
25
(SR)
18
]
[Au]
1+12
{[Au
2
(SR)
3
]
6
}
Centred icosahedron with 6 c type staples
25 18
1 12
0 6 0 8 5(+1)
[Au
38
(SR)
24
] [Au]
5+18
{[Au(SR)
2
]
3
[Au
2
(SR)
3
]
6
} Two icosahedra sharing a triangular face with 3 b and 6 c type staples
38 24
5 18
3 6 0
14 9
[Au
102
(SR)
44
] [Au]
79
{[Au(SR)
2
]
19
[Au
2
(SR)
3
]
2
} Marks dodecahedron and 19 b type and 2 c type staples
102 44 39 40 19 2 0
58 21
Cuboctahedra based
[Au
28
(SR)
20
] [Au]
2+18
{[Au
2
(SR)
3
]
4
(
2
-SR)
8
}
ʼ
Two cuboctahedra sharing six faces 4 type c staples
28 20
2 18
0 4 8
8 12
2
-SR)
12
}
[Au
36
(SR)
24
] [Au]
4+24
{[Au
2
(SR)
3
]
4
(
ʼ
Cuboctahedral with central tetrahedron and 2 type c staples
36 24
4 24 0 4 12
12 16
