Geoscience Reference
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t k
Surface area = A
u
Figure 16.4 The flow of
momentum in the X direction
transferred by molecular
diffusion into and out of a
small volume when the
magnitude of the horizontal
velocity is changing along the
Z axis.
Acceleration
Thickness = d z
Different gradients
and hence different
fluxes
t k
Consider the small element of air shown in Fig. 16.4 which has cross-
sectional area A and thickness dz and therefore has a volume V = ( Adz ). There
is a flow of kinematic momentum (velocity) in the X direction of t k per unit
area from below the volume element that is different to the flow t k
per unit
area leaving from above. This difference will generate an acceleration of the
volume V in the X direction that is equal to the difference between the two
kinematic fluxes, thus:
u
V
=
A
tt
′ −
(16.17)
k
k
t
Because the volume element is thin, t k
can be estimated from t k and the thickness
dz by taking the first two terms in a Taylor expansion, thus:
t
tt d
=+
'
k
z
(16.18)
k
k
z
Substituting Equation (16.18) and V = ( Adz ) into Equation (16.17) gives:
u
∂τ
k
(
Az
δ
)
=
A
τ
+
δ
z
− τ
(16.19)
k
k
t
z
and substituting Equation (16.16) into Equation (16.19) and simplifying gives:
2
u
u
(16.20)
2
t
z
The above analysis only considers the diffusion along the Z axis of velocity (i.e.
kinematic momentum) in the X direction, but analogous analyses can be made for
diffusion along the X and Y axes of kinematic momentum in the X direction.
Consequently, the total rate of change in kinematic momentum in the X direction
associated with molecular diffusion processes that must be included as a 'forcing
 
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